Issue 23, 1998

Quantitative gas-phase electrophilicities of the dihalogen molecules XY = F2, Cl2, Br2, BrCl and ClF

Abstract

Intermolecular stretching force constants kσ determined from the rotational spectra of complexes B···XY, where B is one of the Lewis bases CO, C2H2, C2H4, HCN, H2S and NH3 and XY is a dihalogen F2, Cl2, Br2, BrCl and ClF, are used to establish a quantitative scale of gas-phase electrophilicities EXY of the halogens.

Article information

Article type
Paper

Chem. Commun., 1998, 2585-2586

Quantitative gas-phase electrophilicities of the dihalogen molecules XY = F2, Cl2, Br2, BrCl and ClF

A. C. Legon, Chem. Commun., 1998, 2585 DOI: 10.1039/A807288D

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