Syntheses of two novel halomethanetriyltrisphosphonic acids are based on an improved preparation of methanetriyltrisphosphonic acid: pKas for their second acidic dissociations show they are ‘supercharged’ relative to pyrophosphoric acid, PPi, while X-ray crystallographic analysis of fluoromethanetriyltrisphosphonic acid establishes its isosteric character relative to PPi.
X. Liu, H. Adams and G. Michael Blackburn, Chem. Commun., 1998, 2619 DOI: 10.1039/A807162D
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