The hydrogenation of ethyl pyruvate to (S)-ethyl lactate (up to 70% ee) over a Pt/Al2O3 catalyst using α-isocinchonine as a modifier strongly supports the structure of the intermediate complex [cinchona alkaloid (open conformer)–pyruvate 1:1 complex] of this type of reactions.
M. Bartók, K. Felföldi, M. Bartók, B. Török and T. Bartók, Chem. Commun., 1998, 2605 DOI: 10.1039/A807039C
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