Issue 22, 1998
From the journal:

Chemical Communications

Molecular structures of 1,12-B12H10(CO)2 and its dihydrate 1,12-B12H10[C(OH)2]2—a novel bis-carbene complex

Mark A. Fox,   Judith A. K. Howard,   Janet M. Moloney  and  Kenneth Wade  

Abstract

Crystal structures of the dicarbonyl 1,12-B12H10(CO)2 and its hydrated form 1,12-B12H10(CO2H2)2·4H2O show little π-bond character in their B–C bonds but contain significant distortions from the regular B12 icosahedron geometry; the hydrate, until now thought to be a hydroxonium salt, contains dihydroxycarbene (‘protonated carboxylic acid’) ligands C(OH)2.

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Article information

DOI
https://doi.org/10.1039/A806898D
Article type
Paper

Chem. Commun., 1998, 2487-2488

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Molecular structures of 1,12-B12H10(CO)2 and its dihydrate 1,12-B12H10[C(OH)2]2—a novel bis-carbene complex

M. A. Fox, J. A. K. Howard, J. M. Moloney and K. Wade, Chem. Commun., 1998, 2487 DOI: 10.1039/A806898D

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