Issue 21, 1998

Chloride ion effects on kinetic resolution in Pd-catalysed allylic alkylation

Abstract

Chloride ion (5 mol%) accelerates and stabilises the oxidative addition of the slow-reacting enantiomer of cyclopentenyl pivaloate to Pd0 complexes bearing the Trost modular ligand.

Article information

Article type
Paper

Chem. Commun., 1998, 2321-2322

Chloride ion effects on kinetic resolution in Pd-catalysed allylic alkylation

G. C. Lloyd-Jones and S. C. Stephen, Chem. Commun., 1998, 2321 DOI: 10.1039/A806324I

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