Issue 18, 1998

Metal catalyst-free by design. The synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction

Abstract

Amides can be synthesized from alkyl iodides and amines in the presence of CO (20–25 atm), without using transition metal catalyst; the radical cascade is initiated thermally using AIBN and allyltributyltin.

Article information

Article type
Paper

Chem. Commun., 1998, 1953-1954

Metal catalyst-free by design. The synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction

I. Ryu, K. Nagahara, N. Kambe, N. Sonoda, S. Kreimerman and M. Komatsu, Chem. Commun., 1998, 1953 DOI: 10.1039/A805815F

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