Metal-catalysed addition of B2cat′2 (cat′ = 4-But-1,2-O2C6H3) to ketimines affords N-borylenamines and HBcat′. Analogous catalysed reactions of ketimines with HBcat′ in tetrahydrofuran afford multiply borated products, providing the first examples of metal-catalysed hydroboration of enamines.
T. M. Cameron, R. Tom Baker and S. A. Westcott, Chem. Commun., 1998, 2395 DOI: 10.1039/A805792C
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