Issue 19, 1998

Bismuth(III) thioether chemistry: the synthesis and structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n·nH2O, a highly unusual network involving Bi4Cl4 rings and bridging dithioether ligands

Abstract

The structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n·nH2O involves Bi4Cl121-MeSCH2CH2CH2SMe)4 tetrameric units which are linked by bridging dithioether ligands to give a three-dimensional polymeric network; the Bi4Cl4 core is an eight-membered heterocycle which adopts an open cradle conformation.

Article information

Article type
Paper

Chem. Commun., 1998, 2159-2160

Bismuth(III) thioether chemistry: the synthesis and structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n·nH2O, a highly unusual network involving Bi4Cl4 rings and bridging dithioether ligands

A. R. J. Genge, W. Levason and G. Reid, Chem. Commun., 1998, 2159 DOI: 10.1039/A805674I

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