Bismuth(III) thioether chemistry: the synthesis and structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n·nH2O, a highly unusual network involving Bi4Cl4 rings and bridging dithioether ligands
Abstract
The structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n·nH2O involves Bi4Cl12(η1-MeSCH2CH2CH2SMe)4 tetrameric units which are linked by bridging dithioether ligands to give a three-dimensional polymeric network; the Bi4Cl4 core is an eight-membered heterocycle which adopts an open cradle conformation.
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