The product of the reaction between [Ru(H2O)6]2+ and pressurized H2 in water is [Ru(H2O)5(H2)]2+ whose nature was unambiguously demonstrated by 1H and 17O NMR and which is the first characterized dihydrogen aqua complex.
N. Aebischer, U. Frey and A. E. Merbach, Chem. Commun., 1998, 2303 DOI: 10.1039/A805579C
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