Issue 19, 1998

Dramatic rate acceleration in titanocene catalyzed epoxide openings: cofactors and Lewis acid cocatalysis

Abstract

High synthetic efficiency concerning yield and catalytic turn-over in intermolecular C–C bond forming reactions of radicals derived from epoxides can be achieved by means of hydrogen bonding with cofactors or by Lewis acid cocatalysis.

Article information

Article type
Paper

Chem. Commun., 1998, 2143-2144

Dramatic rate acceleration in titanocene catalyzed epoxide openings: cofactors and Lewis acid cocatalysis

A. Gansäuer and H. Bluhm, Chem. Commun., 1998, 2143 DOI: 10.1039/A805246H

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