A new type of rhenium condensed cluster [Re9Se11Br6]2– has been synthesized by the reaction of Re3Br9 and PbSe at 550 °C and structurally characterised; the structure of [Re9Se11Br6]2– contains the bioctahedral rhenium cluster Re9 which can be considered as the result of progressive uniaxial condensation of three Re3 clusters.
V. E. Fedorov, S. S. Yarovoi, Y. V. Mironov, V. E. Fedorov and M. R. J. Elsegood, Chem. Commun., 1998, 1861 DOI: 10.1039/A804967J
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