The reaction of K[HB(3-Butpz)3] with GaI3 resulted in breakdown of the ligand and formation of a novel Ga/O cluster. This compound can be described as four edge-sharing Ga/O,N octahedra or as two face sharing partial Ga/O heterocubanes, i.e. a quasi double heterocubane.
P. Hodge and B. Piggott, Chem. Commun., 1998, 1933 DOI: 10.1039/A804460K
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