The reaction of metal carbonyls with readily-available phosphoramidate anions provides a new route to metal isonitriles; in particular, enantiomerically pure isonitrile complexes are easily accessed by this method.
S. E. Gibson (née Thomas) and M. F. Ward, Chem. Commun., 1998, 1671 DOI: 10.1039/A804302G
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