A hybrid between the Prussian Blue and Creutz–Taube mixed valent species is presented in the form of the bmtz-bridged bis[tetracyanoiron(+2.5)] complex 13– [bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine] which exhibits a very large comproportionation constant of 1014 and a delocalised structure, according to UV–VIS–NIR–IR spectroelectrochemistry in acetonitrile solution.
M. Ketterle, W. Kaim and J. Fiedler, Chem. Commun., 1998, 1701 DOI: 10.1039/A804279I
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