Several titanium derivatives supported on silica have been investigated as catalysts in the sulfide→sulfoxide oxidation; the supported titanium/tartaric acid catalyst is highly suited to reactions carried out with H2O2, leading to high yields and high sulfoxide/sulfone selectivities, while small asymmetric inductions (up to 13%) are observed.
J. M. Fraile, B. Lázaro and J. A. Mayoral, Chem. Commun., 1998, 1807 DOI: 10.1039/A804180F
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