Aryl bromides can efficiently react with some metallocenes, typically zirconocene dichloride, in the presence of a palladium/phosphine catalyst system and an appropriate base to produce the corresponding pentaarylated cyclopentadienes.
M. Miura, S. Pivsa-Art, T. Satoh, M. Nomura, M. Miura, G. Dyker and J. Heiermann, Chem. Commun., 1998, 1889 DOI: 10.1039/A804026E
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