Ascorbate reacts with S-nitrosothiols at pH 7.4 via two pathways, in which ascorbate (at low concentration) acts as a reducing agent generating CuI, and (at high concentration) acts as a nucleophile, attacking the nitroso group.
A. J. Holmes, Chem. Commun., 1998, 1711 DOI: 10.1039/A803983F
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