Irradiation of a benzene solution containing methyl 2-(2,3-dimethylbut-2-enyloxymethyl)naphthalene-1-carboxylate 1 gave an eight-membered keto ether 2 as the main product via a novel 1,9-hydrogen abstraction of the ester carbonyl group.
K. Mizuno, S. Konishi and Y. Yoshimi, Chem. Commun., 1998, 1659 DOI: 10.1039/A803711F
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