Exo-ligands based on functionalisation of diazacyclic cores of variable size by two pyridines has been achieved; under self-assembly conditions, their ability to form metallamacrocycles in the presence of PdII or AgII was demonstrated by X-ray crystallography.
R. Schneider, M. Wais Hosseini, J. Planeix, A. De Cian and J. Fischer, Chem. Commun., 1998, 1625 DOI: 10.1039/A803166E
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