The non-concerted jumping of two phosphine ligands from one metal center to the other in [Mo2Cl4(PH3)4] is found to be <30 kcal mol–1 (1 cal = 4.184 J) energy costing process (DFT calculations).
Y. Jean and A. Lledos, Chem. Commun., 1998, 1443 DOI: 10.1039/A802706D
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