The disiloxane O{SiMe2CH(SiMe3)2}2 is readily metallated by LiMe in thf (thf = tetrahydrofuran) to give the compound S![[upper bond 1 start]](https://www.rsc.org/images/entities/char_e010.gif)
iMe2C(SiMe)3LiC(SiMe3)2SiMe2O![[upper bond 1 end]](https://www.rsc.org/images/entities/char_e011.gif)
Li(thf)2, the crystal structure of which is reported.
C. Eaborn, S. M. El-Hamruni and P. B. Hitchcock, Chem. Commun., 1998, 1277 DOI: 10.1039/A802553C
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