Acid–base reaction at the bridge in a donor–acceptor molecule can influence intramolecular electron-transfer reactions; this has been demonstrated in boronate ester bridged zinc porphyrin–diimide dyads in which intramolecular electron transfer reaction has been completely suppressed by coordination of F– on the bridge boron.
H. Shiratori, A. Osuka, T. Ohno, K. Nozaki, I. Yamazaki and Y. Nishimura, Chem. Commun., 1998, 1539 DOI: 10.1039/A802473A
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