The electrochemical–hydrothermal synthesis of a new mixed-valence oxide BaV7O16·nH2O (n ≈ 4.4) with [V7O16] layers containing both vanadium oxygen tetrahedra and distorted octahedra is reported.
X. Wang, L. Liu and A. J. Jacobson, Chem. Commun., 1998, 1009 DOI: 10.1039/A802059K
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