The first total synthesis of aglaiastatin has been accomplished using pyrrolopyrimidinone construction by simultaneous nucleophilic attack of a nitrogen unit at the carbonyl group and the acyl iminium ion.
T. Watanabe, T. Takeuchi, S. Kohzuma, K. Umezawa and M. Otsuka, Chem. Commun., 1998, 1097 DOI: 10.1039/A801502C
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