N-Aryl-N′-trimethylsulfurdiimides (aryl = 2,6-F2C6H3, 2-FC6H4) react with TASF to give quantitatively the corresponding TAS salts with the ArNSN– anions (2a, 2b), isoelectronic with arylthionylimides 3; because of the short terminal SN bond the anions should be regarded as thiazylamide rather than sulfurdiimide anions.
A. V. Zibarev, A. V. Zibarev, E. Lork and R. Mews, Chem. Commun., 1998, 991 DOI: 10.1039/A801262H
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