The alcoholysis of the title compound with RO–/ROH gives the 1,3,2-diazaphospholidine derivative via the cleavage of the P–N(2) bond, while under acidic catalysis the P–N(5) bond is broken leading to the eight-membered monocyclic product, which can isomerize via a new type of rearrangement to the former five-membered system.
X. Y. Mbianda and P. H. Van Rooyen, Chem. Commun., 1998, 741 DOI: 10.1039/A800836A
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