A highly enantioselective total synthesis of (+)-furanomycin 24 has been achieved via the mercury cation-mediated cyclizations of γ-hydroxy alkene 4 and homoallylic trichloroacetimidate 11 to install the trans-2,5-disubstituted tetrahydrofuran and the (αS)-amino acid side chain, respectively.
S. Ho Kang and S. Bae Lee, Chem. Commun., 1998, 761 DOI: 10.1039/A800727F
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