SF6-photosensitised IR laser pyrolysis of W(CO)6 in the gas phase at moderate temperatures leads to unsaturated W(CO)n species; these prove to be very effective and selective abstractors of Cl atoms from a wide range of organic substrates, and offer a low energy and clean route into gas phase organic radical chemistry.
G. R. Allen and N. D. Renner, Chem. Commun., 1998, 703 DOI: 10.1039/A708737C
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