2 H NMR, EPR, computational and product analyses of the photolysis of 2,4-diphenylpentan-3-one (DPP) adsorbed on MFI size/shape selective zeolites are consistent with supramolecular structural changes as a function of surface coverage that provide a novel method for the generation of persistent diffusing organic free radicals.
N. J. Turro, A. McDermott, X. Lei, W. Li, A. McDermott, X. Lei, L. Abrams, M. Francesca Ottaviani, H. Støgård Beard, K. N. Houk, B. R. Beno and P. S. Lee, Chem. Commun., 1998, 697 DOI: 10.1039/A708691A
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