Issue 6, 1998

Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

Abstract

Single crystal X-ray analysis of the hexanuclear silver(I) complex Ag6[o-Ph2P(C6H4CO2)-O,P]6, synthesized by treatment of Ag(CF3SO3) with N(CH2CH2NH2)3, 1,3-dicyclohexylcarbodiimide (DCC) and o-Ph2PC6H4(CO2H) in 1:1:3:3 molar ratio in ethanol, shows that the complex is centrosymmetric and consists of three independent silver(I) centres linking together via non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate groups.

Article information

Article type
Paper

Chem. Commun., 1998, 673-674

Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

W. Wong, L. Zhang and W. Wong, Chem. Commun., 1998, 673 DOI: 10.1039/A708227D

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