The preparation of a new optically active phosphinoacyloxazolidinone, based on the enantioselective hydrogenation of a 4-methylene-N-propionyloxazolidinone in the presence of [(R)-BINAP]Ru(O2CCF3)2 catalyst followed by stereoselective phosphinylation, is reported.
P. Le Gendre, F. Jérôme, C. Bruneau and P. H. Dixneuf, Chem. Commun., 1998, 533 DOI: 10.1039/A708223A
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