Issue 2, 1998
From the journal:

Chemical Communications

Synthesis and structure of [{(ButO)2Sb3(µ-NCy)3(µ3-NCy)}K·η6-C6H5Me]; a sandwich complex containing a unique SbIIInido cage anion (Cy = cyclohexyl, C6H11)

Michael A. Beswick,   Nick Choi,   Alexander D. Hopkins,   Mary McPartlin,   Michael A. Paver  and  Dominic S. Wright  

Abstract

Reaction of the terminal NMe2 groups of the spiro antimony(III) imido anion [{(Me2N)Sb(µ-NCy)}2Sb]– with ButOH results in major rearrangement in the Sb–N framework as witnessed in the structure of the sandwich complex [{(ButO)2Sb3(µ-NCy)3(µ3-NCy)}K·η6-C6H5Me] 1, containing the novel nido cage anion [(ButO)2Sb3(µ-NCy)3(µ3-NCy)]–.

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Article information

DOI
https://doi.org/10.1039/A708083B
Article type
Paper

Chem. Commun., 1998, 261-262

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Synthesis and structure of [{(ButO)2Sb3(µ-NCy)3(µ3-NCy)}K·η6-C6H5Me]; a sandwich complex containing a unique SbIIInido cage anion (Cy = cyclohexyl, C6H11)

M. A. Beswick, N. Choi, A. D. Hopkins, M. McPartlin, M. A. Paver and D. S. Wright, Chem. Commun., 1998, 261 DOI: 10.1039/A708083B

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