Issue 2, 1998
From the journal:

Chemical Communications

First complexes with cuboidal-type M 4Te 4 (M = Mo, W) cluster cores: synthesis and structure of K 7[Mo 4(µ 3-Te) 4(CN) 12]·11H 2O and K 6[W 4(µ 3-Te) 4(CN) 12]·5H 2O

Vladimir P. Fedin,   Irina V. Kalinina,   Alexander V. Virovets,   Nina V. Podberezskaya  and  A. Geoffrey Sykes  

Abstract

High-temperature reactions of Mo 3Te 7I 4 or WTe 2 with KCN at 450 °C produce M 4Te 4 cubane-type complexes, isolated here as K 7[Mo 4(µ 3-Te) 4(CN) 12]·11H 2O and K 6[W 4(µ 3-Te) 4(CN) 12]·5H 2O in high yields, and characterized by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/A707995H
Article type
Paper

Chem. Commun., 1998, 237-238

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First complexes with cuboidal-type M 4Te 4 (M = Mo, W) cluster cores: synthesis and structure of K 7[Mo 4(µ 3-Te) 4(CN) 12]·11H 2O and K 6[W 4(µ 3-Te) 4(CN) 12]·5H 2O

V. P. Fedin, I. V. Kalinina, A. V. Virovets, N. V. Podberezskaya and A. Geoffrey Sykes, Chem. Commun., 1998, 237 DOI: 10.1039/A707995H

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