Issue 2, 1998
From the journal:

Chemical Communications

Regiocontrol in palladium-catalysed allylic alkylation by addition of lithium iodide

Motoi Kawatsura,   Yasuhiro Uozumi  and  Tamio Hayashi  

Abstract

Regioselectivity in the palladium-catalysed allylic alkylation of 1-arylprop-2-enyl acetates [ArCH(OAc)CH[double bond, length half m-dash]CH2] or (E)-3-phenylprop-2-enyl acetate (PhCH[double bond, length half m-dash]CHCH2OAc) with sodium enolates of soft carbon nucleophiles is controlled by addition of a catalytic amount of lithium iodide to give lienar products [(E)-ArCH[double bond, length half m-dash]CHCH2Nu] exclusively; their branch isomers [ArCH(Nu)CH[double bond, length half m-dash]CH2] were not detected.

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Article information

DOI
https://doi.org/10.1039/A707652E
Article type
Paper

Chem. Commun., 1998, 217-218

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Regiocontrol in palladium-catalysed allylic alkylation by addition of lithium iodide

M. Kawatsura, Y. Uozumi and T. Hayashi, Chem. Commun., 1998, 217 DOI: 10.1039/A707652E

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