Reaction of C60Ph5Cl with cyanogen bromide results in replacement of the chlorine by BrCN and ring closure between the addend and an adjacent phenyl ring, giving a 1-bromoisoquinoline derivative of [60]fullerene; this readily undergoes nucleophilic replacement of Br by OH to give the corresponding 1-isoquinolone derivative.
A. K. Abdul-Sada, A. G. Avent, D. R. M. Walton and O. B. Woodhouse, Chem. Commun., 1998, 307 DOI: 10.1039/A707430A
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