The enantiomers of the first cagewise inherently asymmetric C 60 derivative, i.e. N-MEM (MEM = 2-methoxyethoxymethyl) keto lactam 1, have been separated by HPLC and their chiroptical properties compared with data obtained from C 60 derivatives that are dissymmetric or asymmetric due to chiral addends.
J. C. Hummelen, M. Keshavarz-K, J. L. J. van Dongen, R. A. J. Janssen, E. W. Meijer and F. Wudl, Chem. Commun., 1998, 281 DOI: 10.1039/A707274K
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