Issue 1, 1998
From the journal:

Chemical Communications

Stereoselective formation of (Z)-γ-substituted allylsilanes by the titanocene(II)-promoted reaction of thioacetals with trialkyl(allyl)silanes

Tooru Fujiwara,   Mayumi Takamori  and  Takeshi Takeda  

Abstract

The reaction of organotitanium species prepared by the desulfurizative titanation of thioacetals with (C5H5)2Ti[P(OEt)3]2 in the presence of trialkyl(allyl)silanes gives γ-substituted allylsilanes with Z stereoselectivity.

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Article information

DOI
https://doi.org/10.1039/A707177I
Article type
Paper

Chem. Commun., 1998, 51-52

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Stereoselective formation of (Z)-γ-substituted allylsilanes by the titanocene(II)-promoted reaction of thioacetals with trialkyl(allyl)silanes

T. Fujiwara, M. Takamori and T. Takeda, Chem. Commun., 1998, 51 DOI: 10.1039/A707177I

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