Molecular oxygen states present at Ag(111) surfaces when dioxygen is coadsorbed with ammonia at 80 K are characterised by vibrational loss features at 1488 and 1640 cm–1. The former is suggested to be associated with the NH3···O2δ– complex, a key intermediate in the oxidation pathway.
A. F. Carley, P. R. Davies, M. W. Roberts and S. Yan, Chem. Commun., 1998, 35 DOI: 10.1039/A707124H
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