A biomimetic methyl transfer, analogous to a tetrahydrofolate-to-homocystein transfer, is simulated by the reaction of methylammonium salts with arylthiolatocobaloxime; the mechanism proposed is an electron transfer from the cobaloxime to the ammonium ion followed by radical substitution of the methyl group.
M. Tada, T. Kambe, M. Tada and Y. Inouye, Chem. Commun., 1998, 41 DOI: 10.1039/A706823I
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