Incorporation of labelled acetates and serine into pramanicin 1 in Stagonospora sp. ATCC 74235 shows that the carbon skeleton of 1 is derived from eight acetate units and a serine residue, implying that the biosynthesis of 1 proceeds via an acyl–tetramic acid intermediate 3.
P. H. M. Harrison, D. W. Hughes and R. William Riddoch, Chem. Commun., 1998, 273 DOI: 10.1039/A706799B
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