Approximate absolute rate constants for the abstraction of bromine from a series of aryl bromides by stannyl radicals have been determined: 2,4,6-tri-tert-butylbromobenzene and 2,4,6-triphenylbromobenzene are found to be unusually reactive, most likely owing to steric acceleration.
F. Recupero, Chem. Commun., 1998, 189 DOI: 10.1039/A706753D
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