Issue 9, 1997
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Formation of silylketenes via a 1,3-silyl shift. A theoretical study

Magali Oblin,   Frédéric Fotiadu,   Michel Rajzmann  and  Jean-Marc Pons  

Abstract

Ab initio and semiempirical calculations show that the formation of silylketenes from silyloxyacetylenes by a 1,3-silyl shift should occur through a concerted closed-shell mechanism involving retention (rather than inversion) of configuration at the silicon centre.

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Article information

DOI
https://doi.org/10.1039/A703439C
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 1621-1624

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Formation of silylketenes via a 1,3-silyl shift. A theoretical study

M. Oblin, F. Fotiadu, M. Rajzmann and J. Pons, J. Chem. Soc., Perkin Trans. 2, 1997, 1621 DOI: 10.1039/A703439C

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