Issue 9, 1997

Photochemical reactions of alkoxy-containing-alkyl phenylglyoxylates: remote hydrogen abstraction

Abstract

A series of alkoxy-containing-alkyl phenylglyoxylates have been synthesized and their photochemical reactions studied. The intention was to probe structural requirements for remote hydrogen abstraction. Products resulting from 1,10- and 1,11-hydrogen abstraction were isolated from the photochemical reactions of 4′-methoxybutyl phenylglyoxylate 3d and 5′-benzyloxypentyl phenylglyoxylate 3h respectively. Products resulting from Norrish Type II and intermolecular hydrogen abstraction reactions were also isolated. Triplet lifetimes of representative compounds were measured by laser flash photolysis.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 1751-1754

Photochemical reactions of alkoxy-containing-alkyl phenylglyoxylates: remote hydrogen abstraction

S. Hu and D. C. Neckers, J. Chem. Soc., Perkin Trans. 2, 1997, 1751 DOI: 10.1039/A700948H

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