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Issue 14, 1997
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Haem d1: stereoselective synthesis of the reducedform of its parent macrocycle using the original coupling strategy

Abstract

A substituted isobacteriochlorin, which corresponds structurally to the reduced metal-free macrocycle of haem d1, has been synthesised by a stereoselective route in which the final step is a photochemical 18π-electron antarafacial cyclisation of an open-chain precursor.

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Article type: Paper
DOI: 10.1039/A700652G
Citation: J. Chem. Soc., Perkin Trans. 1, 1997,0, 2099-2110

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    Haem d1: stereoselective synthesis of the reduced form of its parent macrocycle using the original coupling strategy

    C. J. Aucken, F. J. Leeper and A. R. Battersby, J. Chem. Soc., Perkin Trans. 1, 1997, 0, 2099
    DOI: 10.1039/A700652G

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