Issue 16, 1997
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Novel ring transformation of nitropyrimidinone; synthetic equivalent of α-nitroformylacetic acid

Nagatoshi Nishiwaki,   Hui-Ping Wang,   Kengo Matsuo,   Yasuo Tohda  and  Masahiro Ariga  

Abstract

3-Methyl-5-nitropyrimidin-4(3H)-one reacts with ketones in the presence of ammonium salts to afford disubstituted pyrimidines and disubstituted 3-nitro-2-pyridones in a novel ring transformation reaction; nitropyrimidinone behaves as an activated diformylamine in the former case, and as a synthetic equivalent of α-nitroformylacetic acid in the latter case.

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Article information

DOI
https://doi.org/10.1039/A704354F
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 2261-2262

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Novel ring transformation of nitropyrimidinone; synthetic equivalent of α-nitroformylacetic acid

N. Nishiwaki, H. Wang, K. Matsuo, Y. Tohda and M. Ariga, J. Chem. Soc., Perkin Trans. 1, 1997, 2261 DOI: 10.1039/A704354F

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