Issue 23, 1997

Application of PdII-catalysed oxidative cyclisation of hydroxy(vinyl)furan: synthesis of (5R)-diastereomer of (+)-goniofufurone

Abstract

A convenient synthesis of the (5R)-diastereomer of (+)-goniofufurone 5 from D-mannose has been completed. A key step is the intramolecular PdCl2-catalysed oxidative cyclisation of hydroxy(vinyl)furan 6 to lactol 16.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 3567-3572

Application of PdII-catalysed oxidative cyclisation of hydroxy(vinyl)furan: synthesis of (5R)-diastereomer of (+)-goniofufurone

H. Babu Mereyala, R. Reddy Gadikota and R. Krishnan, J. Chem. Soc., Perkin Trans. 1, 1997, 3567 DOI: 10.1039/A703905K

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