Issue 24, 1997

Intramolecular photocyclisation reactions of 5-tert-butyldimethylsilyloxymethyl-3-(3-formylpropyl)furan-2(5H )-one: formation of bicyclic and spirobicyclic lactones

Abstract

5-tert-Butyldimethylsilyloxymethyl-3-(3-formylpropyl)furan-2(5H )-one has been synthesised and upon irradiation yields either one homochiral bicyclic lactone or a mixture of spirobicyclic lactones (in modest yield) depending upon the irradiation conditions.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 3651-3656

Intramolecular photocyclisation reactions of 5-tert-butyldimethylsilyloxymethyl-3-(3-formylpropyl)furan-2(5H )-one: formation of bicyclic and spirobicyclic lactones

D. Brown, M. G. B. Drew and J. Mann, J. Chem. Soc., Perkin Trans. 1, 1997, 3651 DOI: 10.1039/A703745G

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