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Issue 14, 1997
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Synthesis and characterization of 2-methoxy-2H-azepines: the first isolation of 2-azanorcaradiene, the valence isomer of 3H-azepine

Abstract

The selective formation of 2-methoxy-2H-azepine from 3H-azepines, via a likely azatropylium cation, is reported; the first isolation of 2-azanorcaradiene, which is considered to be the valence isomer of 3H-azepine, is also described.

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Article type: Paper
DOI: 10.1039/A703709K
J. Chem. Soc., Perkin Trans. 1, 1997, 2015-2018

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    Synthesis and characterization of 2-methoxy-2H-azepines: the first isolation of 2-azanorcaradiene, the valence isomer of 3H-azepine

    K. Satake, Y. Tawada, H. Okamoto and M. Kimura, J. Chem. Soc., Perkin Trans. 1, 1997, 2015
    DOI: 10.1039/A703709K

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