Issue 16, 1997

Towards a synthesis of C3-tribenzohemifullerene, a C42H18 fragment of [60]fullerene

Abstract

A short, simple synthesis of C3-trinaphthotriphenylene 6, C42H24, from readily available precursors involving threefold Wittig reactions and threefold oxidative photocyclizations is reported; flash vacuum pyrolysis of 6 in the quest for C3-tribenzohemifullerene 5, C42H18, has so far led only to the formation of monobridged product 12, C42H22.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 2269-2272

Towards a synthesis of C3-tribenzohemifullerene, a C42H18 fragment of [60]fullerene

G. Mehta, G. Panda, S. R. Shah and A. C. Kunwar, J. Chem. Soc., Perkin Trans. 1, 1997, 2269 DOI: 10.1039/A702911J

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