Issue 16, 1997

Some single electron-transfer reactions of arylimines

Abstract

When treated with suitable alkyllithiums, arylimines may undergo single electron-transfer and conjugative substitution in the aryl ring, as well as nucleophilic addition to the imine bond. Multiple substitutions by tert-butyl radicals are noted, giving rise to rearranged and oxidized products, including cycloadducts.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 2337-2344

Some single electron-transfer reactions of arylimines

D. W. Brown, M. Lindquist, M. F. Mahon, B. Malm, G. N. Nilsson, A. Ninan, M. Sainsbury and C. Westerlund, J. Chem. Soc., Perkin Trans. 1, 1997, 2337 DOI: 10.1039/A701947E

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